Item Details

abstract

An unusual hexameric structure has been isolated from exposure of 3-BF3-1-Phenyl-1,3-Butadiene to air and moisture in an attempt to obtain crystals of the starting compound. Formation of this hexamer is rationalized and its structural features are compared to other B(OR)2 substituted cyclohexane and benzene ring containing structures.

citation

12 (issue)

63 (volume)

contributor

De, Subhasis (author)

Day, Cynthia S. (author)

Welker, Mark E. (author)

date

2011-08-29T18:09:09Z (accessioned)

2011-08-29T18:09:09Z (available)

2007 (issued)

identifier

An Unusual Oligimerization/Oxidation Reaction of a 3-Boron-Substituted 1-Phenyl-1,3-Butadiene Produces a Hexameric Product. Subhasis De, Cynthia S. Day, and Mark E. Welker* Acta Cryst. 2007 C63, o729-o730. Available at http://onlinelibrary.wiley.com/doi/10.1107/S0108270107050986/abstract. (citation)

http://hdl.handle.net/10339/36126 (uri)

source

Acta Cyrstallographica Section C

http://onlinelibrary.wiley.com/doi/10.1107/S0108270107050986/abstract (uri)

title

An unusual oligomerization/oxidation reaction of a 3-boron-substituted 1-phenylbuta-1,3-diene produces 6,9,16,19-tetraphenyl-5,15-distyryl-3,13,25,26-tetraoxa-2,12-diborapentacyclo[16.2.2.28,11.12,5.112,15]hexacosa-1(20),7,10,17-tetraene

type

Article