An unusual oligomerization/oxidation reaction of a 3-boron-substituted 1-phenylbuta-1,3-diene produces 6,9,16,19-tetraphenyl-5,15-distyryl-3,13,25,26-tetraoxa-2,12-diborapentacyclo[16.2.2.28,11.12,5.112,15]hexacosa-1(20),7,10,17-tetraene
Welker, Mark E.
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- title
- An unusual oligomerization/oxidation reaction of a 3-boron-substituted 1-phenylbuta-1,3-diene produces 6,9,16,19-tetraphenyl-5,15-distyryl-3,13,25,26-tetraoxa-2,12-diborapentacyclo[16.2.2.28,11.12,5.112,15]hexacosa-1(20),7,10,17-tetraene
- author
- De, Subhasis
- author
- Day, Cynthia S.
- author
- Welker, Mark E.
- abstract
- An unusual hexameric structure has been isolated from exposure of 3-BF3-1-Phenyl-1,3-Butadiene to air and moisture in an attempt to obtain crystals of the starting compound. Formation of this hexamer is rationalized and its structural features are compared to other B(OR)2 substituted cyclohexane and benzene ring containing structures.
- citation
- 12 (issue)
- 63 (volume)
- date
- 2011-08-29T18:09:09Z (accessioned)
- 2011-08-29T18:09:09Z (available)
- 2007 (issued)
- identifier
- An Unusual Oligimerization/Oxidation Reaction of a 3-Boron-Substituted 1-Phenyl-1,3-Butadiene Produces a Hexameric Product. Subhasis De, Cynthia S. Day, and Mark E. Welker* Acta Cryst. 2007 C63, o729-o730. Available at http://onlinelibrary.wiley.com/doi/10.1107/S0108270107050986/abstract. (citation)
- http://hdl.handle.net/10339/36126 (uri)
- source
- Acta Cyrstallographica Section C
- http://onlinelibrary.wiley.com/doi/10.1107/S0108270107050986/abstract (uri)
- type
- Article