Item Details

title

Syntheses of 2-Silicon-Substituted 1,3-Dienes

author

Choudhury, Partha P.

author

Junker, Christopher S.

author

Pidaparthi, Ramakrishna R.

author

Welker, Mark E.

abstract

A number of 2-silicon substituted 1,3–dienes have been prepared by one of three routes: 1) Reactions of 1,3-dienyl Grignard reagents with silyl electrophiles or silyl Grignard reagents with 1,3-dienyl electrophiles; 2) Hydrosilylation of enynes; 3) Enyne cross metathesis. The strengths and limitations of each preparative method are discussed.

description

This manuscript has been accepted for publication in the Journal of Organometallic Chemistry. It was accepted for publication on 24 December 2013, and first published online on 3 January 2014. It is available at http://dx.doi.org/10.1016/j.jorganchem.2013.12.046.

subject

1,3-dienes

metal dienyls

Grignard reactions

hydrosilylation

enyne cross metathesis

date

2014-01-16T17:55:03Z (accessioned)

2014-01-16T17:55:03Z (available)

2014 (issued)

identifier

Choudhury, P.P.; Junker, C.S.; Pidaparthi, R.R.; Welker, M.E. (2014). "Syntheses of 2-Silicon-Substituted 1,3-Dienes." Journal of Organometallic Chemistry, In Press. Accepted manuscript available at http://dx.doi.org/10.1016/j.jorganchem.2013.12.046. (citation)

http://hdl.handle.net/10339/39145 (uri)

identifier

http://dx.doi.org/10.1016/j.jorganchem.2013.12.046 (doi)

publisher

Elsevier

source

Journal of Organometallic Chemistry

type

Article