Syntheses of 2-Silicon-Substituted 1,3-Dienes
Welker, Mark E.
Item Files
Item Details
- abstract
- A number of 2-silicon substituted 1,3–dienes have been prepared by one of three routes: 1) Reactions of 1,3-dienyl Grignard reagents with silyl electrophiles or silyl Grignard reagents with 1,3-dienyl electrophiles; 2) Hydrosilylation of enynes; 3) Enyne cross metathesis. The strengths and limitations of each preparative method are discussed.
- description
- This manuscript has been accepted for publication in the Journal of Organometallic Chemistry. It was accepted for publication on 24 December 2013, and first published online on 3 January 2014. It is available at http://dx.doi.org/10.1016/j.jorganchem.2013.12.046.
- subject
- 1,3-dienes
- metal dienyls
- Grignard reactions
- hydrosilylation
- enyne cross metathesis
- contributor
- date
- 2014-01-16T17:55:03Z (accessioned)
- 2014-01-16T17:55:03Z (available)
- 2014 (issued)
- identifier
- Choudhury, P.P.; Junker, C.S.; Pidaparthi, R.R.; Welker, M.E. (2014). "Syntheses of 2-Silicon-Substituted 1,3-Dienes." Journal of Organometallic Chemistry, In Press. Accepted manuscript available at http://dx.doi.org/10.1016/j.jorganchem.2013.12.046. (citation)
- http://dx.doi.org/10.1016/j.jorganchem.2013.12.046 (doi)
- http://hdl.handle.net/10339/39145 (uri)
- publisher
- Elsevier
- source
- Journal of Organometallic Chemistry
- title
- Syntheses of 2-Silicon-Substituted 1,3-Dienes
- type
- Article