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oai:null:10339/593122026-09-02T14:24:15Zcom_10339_14934col_10339_38132

Goetz, Katelyn Patricia 2016-05-21T08:35:50Z 2017-05-20T08:30:08Z 2016 https://wakespace.lib.wfu.edu/handle/10339/59312 Organic charge-transfer complexes are ordered combinations of charge-donating (D) and charge-accepting (A) compounds. The proximity of the D and A units results in a partial degree of ionicity and a band structure that is a hybrid of the parent compounds, allowing the complex to exhibit interesting physical characteristics. These include metallicity, ambipolar semiconductivity, photoconductivity, ferroelectricity, and more. The focus of this work is to identify several structure-function relationships in charge-transfer complexes pertaining to organic field-effect transistors (OFETs). The materials of focus in these studies are perylene- 7,7,8,8-tetracyanoquinodimethane (perylene-TCNQ), dibenzotetrathiafulvalene-TCNQ (DBTTF-TCNQ), and stilbene-F4TCNQ. en Wake Forest University Charge-Transfer Complexes Organic Electronics Organic Semiconductors Single Crystals Structure-Function Relationships in Organic Charge-Transfer Complexes Dissertation Jurchescu, Oana D Holzwarth, Natalie A.W. Matthews, George E Williams, Richard T Physics 2017-05-20 open.access