Rhodium Catalyzed Tandem Diels-Alder/Hydrolysis Reactions of 2-Boron-Substituted 1,3-Dienes

De, Subhasis; Solano, John M.; Wang, Liqiong; Welker, Mark E.

Rhodium Catalyzed Tandem Diels-Alder/Hydrolysis Reactions of 2-Boron-Substituted 1,3-Dienes

Abstract

2-Boron substituted 1,3 –dienes have been prepared and used in preliminary experiments to demonstrate that it is possible to effect rhodium catalyzed Diels-Alder/hydrolysis tandem reactions.

Keywords

rhodium catalysis, Diels-Alder, transmetallation, boron diene

Citation

Rhodium Catalyzed Tandem Diels-Alder/Hydrolysis Reactions of 2-Boron-Substituted 1,3-Dienes. Subhasis De, John M. Solano, Liqiong Wang and Mark E. Welker, Journal of Organometallic Chemistry, 2009, 694, 2295-2298, http://dx.doi.org/10.1016/j.jorganchem.2009.04.008.